Answer: (i) \(\alpha=3\) or \(\alpha=5\).
(ii) The shortest distance is \(\sqrt{\frac{56}{3}}=4.32\) to 3 significant figures.
(iii) The acute angle is \(19.1^\circ\), or \(0.333\) radians.
Use coordinates \(A=(1,1,3)\), \(B=(3,-1,5)\), \(C=(3,-1,1)\), and \(D=(5,-5,\alpha)\).
Then
\(\overrightarrow{AB}=(2,-2,2)\), \(\overrightarrow{AC}=(2,-2,-2)\), and \(\overrightarrow{CD}=(2,-4,\alpha-1)\).
For the distance between the skew lines \(AB\) and \(CD\), use
\(d=\frac{|\overrightarrow{AC}\cdot(\overrightarrow{AB}\times\overrightarrow{CD})|}{|\overrightarrow{AB}\times\overrightarrow{CD}|}\).
It is convenient to use \((1,-1,1)\) instead of \(\overrightarrow{AB}\), since it is a scalar multiple. Then
\((1,-1,1)\times(2,-4,\alpha-1)=(5-\alpha,3-\alpha,-2)\).
Equivalently, take \((\alpha-5,\alpha-3,2)\) as the normal direction.
Now
\(\overrightarrow{AC}\cdot(\alpha-5,\alpha-3,2)=2(\alpha-5)-2(\alpha-3)-4=-8\).
Also
\(|(\alpha-5,\alpha-3,2)|=\sqrt{(\alpha-5)^2+(\alpha-3)^2+4}=\sqrt{2\alpha^2-16\alpha+38}\).
Since the distance is \(2\sqrt2\),
\(\frac{8}{\sqrt{2\alpha^2-16\alpha+38}}=2\sqrt2\).
Squaring gives
\(64=8(2\alpha^2-16\alpha+38)\), so
\(2\alpha^2-16\alpha+38=8\).
Thus
\(\alpha^2-8\alpha+15=0\), giving
\((\alpha-3)(\alpha-5)=0\).
Hence \(\alpha=3\) or \(\alpha=5\).
Now take \(\alpha=3\), so \(D=(5,-5,3)\). Then
\(\overrightarrow{AD}=(4,-6,0)\) and \(\overrightarrow{AC}=(2,-2,-2)\).
The shortest distance from \(D\) to the line \(AC\) is
\(\frac{|\overrightarrow{AD}\times\overrightarrow{AC}|}{|\overrightarrow{AC}|}\).
Using \((1,-1,-1)\) in place of \(\overrightarrow{AC}\),
\(\overrightarrow{AD}\times(1,-1,-1)=(6,4,2)\), so its magnitude is \(\sqrt{36+16+4}=\sqrt{56}\).
Since \(|(1,-1,-1)|=\sqrt3\), the distance is
\(\sqrt{\frac{56}{3}}=4.32\) to 3 significant figures.
For the angle between the planes, find normal vectors.
For plane \(ABC\), a normal vector is
\(\mathbf{n}_1=(1,-1,-1)\times(1,-1,1)=(-1,-1,0)\).
For plane \(ABD\), using \((1,-1,1)\) and \((2,-3,0)\), a normal vector is
\(\mathbf{n}_2=(1,-1,1)\times(2,-3,0)=(3,2,-1)\).
The acute angle between the planes is the acute angle between their normals, so
\(\cos\theta=\left|\frac{\mathbf{n}_1\cdot\mathbf{n}_2}{|\mathbf{n}_1||\mathbf{n}_2|}\right|=\left|\frac{-3-2+0}{\sqrt2\sqrt{14}}\right|=\frac{5}{\sqrt{28}}\).
Therefore
\(\theta=19.1^\circ\), or \(0.333\) radians.