Answer: After the first collision, \(A\) has speed \(\dfrac15u(4-e)\) and \(B\) has speed \(\boxed{\dfrac45(1+e)u}\). Also \(\boxed{e=\dfrac23}\), and \(B\) does collide with the barrier for a second time.
(i) Take the direction of motion of \(A\) before the first collision as positive. Let the velocities of \(A\) and \(B\) after the first collision be \(v_A\) and \(v_B\).
Conservation of momentum gives
\[4mv_A+mv_B=4mu.\]
So
\[4v_A+v_B=4u.\]
Newton's law of restitution gives
\[v_B-v_A=e(u-0)=eu.\]
Hence \(v_B=v_A+eu\). Substitute this into the momentum equation:
\[4v_A+(v_A+eu)=4u.\]
Therefore
\[5v_A=(4-e)u,\qquad v_A=\frac15u(4-e).\]
Then
\[v_B=v_A+eu=\frac15u(4-e)+eu=\boxed{\frac45(1+e)u}.\]
(ii) When \(B\) hits the fixed barrier, it reverses direction. The coefficient of restitution at the barrier is \(\frac34e\), so the speed of \(B\) after rebounding from the barrier is
\[\frac34e\,v_B=\frac34e\cdot\frac45(1+e)u=\frac35e(1+e)u.\]
After this collision with the barrier, the speeds of \(A\) and \(B\) are equal. Therefore
\[\frac15(4-e)u=\frac35e(1+e)u.\]
Cancel \(u\) and multiply by \(5\):
\[4-e=3e(1+e).\]
So
\[4-e=3e+3e^2,\]
which gives
\[3e^2+4e-4=0.\]
Factorise:
\[(3e-2)(e+2)=0.\]
Since \(e\) must be between \(0\) and \(1\),
\[\boxed{e=\frac23}.\]
(iii) When \(e=\frac23\), the speed of \(A\) after the first collision is
\[v_A=\frac15u\left(4-\frac23\right)=\frac23u.\]
The speed of \(B\) after rebounding from the barrier is also \(\frac23u\), but it is moving in the opposite direction. So immediately before the second collision,
\[v_A=\frac23u,\qquad v_B=-\frac23u.\]
Let the velocities after the second collision be \(w_A\) and \(w_B\). Conservation of momentum gives
\[4w_A+w_B=4\left(\frac23u\right)-\frac23u=2u.\]
Newton's law of restitution gives
\[w_B-w_A=\frac23\left(\frac23u-\left(-\frac23u\right)\right)=\frac89u.\]
Thus \(w_B=w_A+\frac89u\). Substitute into the momentum equation:
\[4w_A+w_A+\frac89u=2u.\]
So
\[5w_A=\frac{10}{9}u,\qquad w_A=\frac29u.\]
Hence
\[w_B=\frac29u+\frac89u=\frac{10}{9}u.\]
This is positive, so \(B\) moves towards the barrier again. Therefore \(B\) collides with the barrier for a second time.