(i) To find \(\overrightarrow{PQ}\):
Since P is the midpoint of DG, and DG is parallel to k, P is at \((0, 6, 3)\).
Q is the center of the square face CBFG, so Q is at \((6, 6, 3)\).
Thus, \(\overrightarrow{PQ} = (6 - 0)\mathbf{i} + (6 - 6)\mathbf{j} + (3 - 3)\mathbf{k} = 6\mathbf{i}\).
(ii) To find \(\overrightarrow{RQ}\):
R is on AB such that AR = 4 cm, so R is at \((4, 0, 0)\).
Thus, \(\overrightarrow{RQ} = (6 - 4)\mathbf{i} + (6 - 0)\mathbf{j} + (3 - 0)\mathbf{k} = 2\mathbf{i} + 6\mathbf{j} + 3\mathbf{k}\).
(iii) To find angle RQP using the scalar product:
The scalar product is given by:
\(\overrightarrow{PQ} \cdot \overrightarrow{RQ} = 6 \times 2 + 0 \times 6 + 0 \times 3 = 12\).
The magnitudes are:
\(|\overrightarrow{PQ}| = \sqrt{6^2} = 6\).
\(|\overrightarrow{RQ}| = \sqrt{2^2 + 6^2 + 3^2} = \sqrt{49} = 7\).
Using the formula:
\(\cos \theta = \frac{\overrightarrow{PQ} \cdot \overrightarrow{RQ}}{|\overrightarrow{PQ}| \times |\overrightarrow{RQ}|} = \frac{12}{6 \times 7} = \frac{12}{42} = \frac{2}{7}\).
Thus, \(\theta = \cos^{-1}\left(\frac{2}{7}\right) \approx 63.2^\circ\).