Let the smaller adjacent angle be \(x^\circ\). The adjacent pair gives \(x+3x=180\), so \(4x=180\) and \(x=45\).

The larger angle is \(3\times45=135^\circ\). Their vertically opposite partners have the same sizes.

Answer

\(45^\circ,135^\circ,45^\circ,135^\circ\) in cyclic order.